High-Performance Supercapacitor Based on the NaOH Activated D-Glucose Derived Carbon

Author:

Wu Chao12,Xu Jiang13,Ding Jianning3,Yuan Ningyi3,Yan Pengtao1,Zhang Ruijun1,Liu Huihan4

Affiliation:

1. State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004, P. R. China

2. North China University of Science and Technology, Tangshan 063009, Hebei, China

3. Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering School of Materials Science and Engineering, Changzhou University, Changzhou 213164, P. R. China

4. Hwa Chong Institution, Bukit Timah Road, 269734, Singapore

Abstract

In this work, a mechanism of catalytic graphitization of D-glucose derived carbon during NaOH activation process is disclosed. The catalytic graphitization is caused by sodium atom, which is produced in the reaction between NaOH and carbon. Due to the combined action of activation and catalytic graphitization resulting from the NaOH, the activated D-glucose derived carbon behaves as a hierarchical micro- and meso-porous structure and has high electrical conductivity. Electrochemical investigations demonstrate that the activated sample exhibits an outstanding rate capability (70% of capacity retention even at a scan rate of 2[Formula: see text]V s[Formula: see text]) and high specific capacitance (106[Formula: see text]F g[Formula: see text]) in 6[Formula: see text]M KOH aqueous electrolyte, which makes it a promising electrode material for high-power supercapacitors.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Hebei Province (CN)

Publisher

World Scientific Pub Co Pte Lt

Subject

Condensed Matter Physics,General Materials Science

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