Research on High Capacitance 3D Structure NiCo2S4 Electrode Material in Supercapacitor

Author:

Ding Meijie1,Wei Zhiqiang1ORCID,Zhu Xiaojun2,Liu Dexue1

Affiliation:

1. State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals and School of Material and Engineering, Lanzhou University of Technology, Lanzhou 730050, P. R. China

2. Jinchuan Group CO., LTD. National Nickel and Cobalt Advanced Materials, Engineering Research Center, Lanzhou 730050, P. R. China

Abstract

To improve the electrochemical performance of the supercapacitor, three electrode nanocomposites, NiO, NiS and NiCo2S4, have been obtained by simple hydrothermal process and high temperature pyrolysis, and further, the impact of electrolytes of different concentrations on electrochemical performance of supercapacitor has been researched. During the research processing, synergistic effect of Ni, Co and S is considered to enhance the electrical conductivity, and promote electron transfer, ion diffusion and structural stability. The experiment results show that bimetallic sulfides display high electrical conductivity, shorter ion diffusion channels, and faster electron and ion transport rate with the feature of topping electrochemical properties of specific capacity, excellent cycling stability and high rate capability, and besides show that it can improve the electrochemical performance of the material by increasing the concentration of electrolyte. The transition-metal sulfides provide a new promising pathway for the expansion of high-performance electrode materials for supercapacitors.

Funder

the National Natural Science Foundation of China

Natural Science Foundation of Jilin Province

Publisher

World Scientific Pub Co Pte Ltd

Subject

Condensed Matter Physics,General Materials Science

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