A NANOSTRUCTURED POLYMORPH OF μ-OXOBIS(PHTHALOCYANINATOIRON(III)) STUDIED BY ANGULAR AND ENERGY DISPERSIVE X-RAY DIFFRACTION-Reference-Cited by-同舟云学术

A NANOSTRUCTURED POLYMORPH OF μ-OXOBIS(PHTHALOCYANINATOIRON(III)) STUDIED BY ANGULAR AND ENERGY DISPERSIVE X-RAY DIFFRACTION

Published:2007-04 Issue:02 Volume:02 Page:121-128
ISSN:1793-2920
Container-title:Nano
language:en
Short-container-title:NANO

Author:

MATASSA ROBERTO¹,BALLIRANO PAOLO²,DONZELLO MARIA PIA¹,ERCOLANI CLAUDIO¹,SADUN CLAUDIA¹,CAMINITI RUGGERO¹

Affiliation:

1. Dipartimento di Chimica, Università degli Studi di Roma "La Sapienza", P.le A. Moro 5, 00185 Roma, Italy

2. Dipartimento di Scienze della Terra, Università degli Studi di Roma "La Sapienza", P.le A. Moro 5, 00185 Roma, Italy

Abstract

A new approach of X-ray diffraction was used to investigate the nanostructured μ-Oxo(2) polymorph of μ-oxo-bis(phthalocyaninatoiron(III)), [ PcFe – O – FePc ]. The packing of the dinuclear units was determined by the Rietveld method on Angular Dispersive X-ray Diffraction (ADXD) data, whereas the intramolecular geometry was optimized by Energy Dispersive X-ray Diffraction (EDXD) exploiting the peculiar strength of those techniques. The dimension of the nanoparticles was estimated from the Fourier transform of the EDXD experimental structural function.

Publisher

World Scientific Pub Co Pte Lt

Subject

Condensed Matter Physics,General Materials Science

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1793292007000398

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1. Finally: The X-ray crystal structure of the illusive unsubstituted iron(III) phthalocyanine μ-oxo(1) dimer. DFT-predicted Mössbauer quadrupole splitting and antiferromagnetic coupling constants for X-ray geometry;Journal of Porphyrins and Phthalocyanines;2024-05

2. Role of MCD and Mössbauer Spectroscopy in the Explanation of the Properties of a Highly Soluble (μ-Oxo)bis[tetra(tert-butyl)(phthalocyaninato)iron(III)] Complex, Its Pyridine Adduct, and Redox Forms Oxidized under Anaerobic Conditions in Non-Coordinating Solvents;Inorganic Chemistry;2023-06-22

3. Organometallic Oligomer Resolved by Radial Distribution Function of X-ray Diffraction Analysis;The Journal of Physical Chemistry B;2010-01-29

4. Long-range solid-state ordering and high geometric distortions induced in phthalocyanines by small fluoroalkyl groups;Dalton Trans.;2009