OPTICAL SPECTROSCOPY AND NONLINEAR TRANSMITTANCE STUDY OF FULLERENE C60 IN MIXTURES WITH 2-CYCLOOCTYLAMINO-5-NITROPYRIDINE (COANP)

Author:

SARKISOV SERGEY S.1,RADOVANOVA ELENA I.2,PETERSON BURL H.1,LEYDERMAN ALEX3,CURLEY MICHAEL1,FLEITZ PAUL A.4

Affiliation:

1. Alabama Agricultural and Mechanical University, Department of Physics, 4900 Meridian St., P.O. Box 1268, Normal, Alabama 35762-1268, USA

2. A. F. Ioffe Physico-Technical Institute RAN, 26 Polytekhnicheskaya, St. Petersburg 194291, Russia

3. Department of Physics, University of Puerto-Rico at Mayaguez, Puerto-Rico 00680, USA

4. Air Force Research Laboratory, Wright-Patterson Air Force Base, Ohio 45433-7702, USA

Abstract

Characterization of the infrared absorption spectrum of the solutions of fullerene C 60 with 2-cyclooctylamino-5-nitropyridine additive has been performed with the focus on possible bonding with the amino-group of the additive. No occurrence of such bonding was found at normal conditions. Also no change of optical absorption in visible region and optical limiting of fullerene due to chemical bonding with the additive was detected. The resulting optical properties of the mixture were simply a sum of the properties of the components for a molar proportion of the additive to fullerene approaching 200:1.

Publisher

World Scientific Pub Co Pte Lt

Subject

Physics and Astronomy (miscellaneous),Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials

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