Affiliation:
1. 90 New Jagruti Colony, Katol Road, Nagpur, India
Abstract
In the present work, an extension of the scaled particle theory (ESPT) for fluid using computer algebra is developed to obtain an equation of state (EOS), for Lennard-Jones fluid. A suitable functional form for surface tension S(r,d,∊) is assumed with intermolecular separation r as a variable, given below: [Formula: see text] where m is arbitrary real number, and d and ∊ are related to physical property such as average or suitable molecular diameter and the binding energy of the molecule respectively. It is found that, for hard sphere fluid ∊ = 0, the above assumption when introduced in scaled particle theory (SPT) frame and choosing arbitrary real number, m = 1/3, the corresponding EOS is in good agreement with the computer simulation of molecular dynamics (MD) result. Furthermore, for the value of m = -1 it gives a Percus–Yevick (pressure), and for the value of m = 1, it corresponds Percus–Yevick (compressibility) EOS.
Publisher
World Scientific Pub Co Pte Lt
Subject
Condensed Matter Physics,Statistical and Nonlinear Physics
Cited by
3 articles.
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