POLYACETYLENE: HELICES, HEAVY SOLITONS AND HYPERCONDUCTIVITY

Author:

BOŽOVIĆ IVAN1

Affiliation:

1. Ginzton Laboratory, Applied Physics Department, Stanford University, Stanford, CA 94305–4090

Abstract

A list of experimental observations (structural, spectroscopical, on transport, isomerization, chemical reactions, etc.) on pristine and doped polyacetylene, (CH)x, which are not compatible with the accepted planar structures and the current theoretical models of charge transport in (CH)x, is compiled. It is proposed that (CH)x is helical and that certain defects (short cis segments) in trans-(CH)x behave like heavy solitons. These assumptions are shown to resolve all the above paradoxes.

Publisher

World Scientific Pub Co Pte Lt

Subject

Condensed Matter Physics,Statistical and Nonlinear Physics

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