A Model of Electron Tunneling to the Surface States in TiO2 with Application to Photocatalysis

Author:

Sidorova T.1

Affiliation:

1. Belarusian State University of Informatics and Radioelectronics, P. Browka 6, 220013 Minsk, Belarus

Abstract

Tunneling transmission of electrons excited by the sun light in the bulk TiO2 to its surface states is simulated. The model is built for the TiO2/Si nanostructure. The tunneling transmission coefficient was calculated by the phase functions method. The surface states are considered to be formed due to adsorption of impurities and organic compounds on TiO2. Energy dependence of the transmission coefficient is influenced by an interference of transmitted and reflected waves under conditions of the complex potential relief.

Publisher

World Scientific Pub Co Pte Lt

Subject

Electrical and Electronic Engineering,Computer Science Applications,Condensed Matter Physics,General Materials Science,Bioengineering,Biotechnology

Reference4 articles.

1. Electrical and photoelectrical properties of photosensitive heterojunctions n-TiO2/p-CdTe

2. Yu. M. Artemiev and V. K. Ryabchuk, Introduction in Heterogenic Photocatalisis (SPbSU Publ., Saint-Petersburg, 1999), pp. 1–303, in Russian.

3. Role of iron and chromium in the photocatalytic activity of titanium dioxide films on stainless steel

4. V. V. Babikov, Phase Fuction Method in the Quantum Mechanics (Nauka, Moscow, 1976), pp. 1–224, in Russian.

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