Affiliation:
1. Department of Mathematics, Rutgers University, Piscataway NJ 08854, USA
Abstract
For classical Hamiltonian N-body systems with mildly regular pair interaction potential (in particular, [Formula: see text] integrability is required), it is shown that when N → ∞ in a fixed bounded domain Λ ⊂ ℝ3, with energy [Formula: see text] scaling as [Formula: see text], then Boltzmann's ergodic ensemble entropy [Formula: see text] has the asymptotic expansion SΛ(N,N2ε) = - N ln N + sΛ(ε) N + o(N). Here, the N ln N term is combinatorial in origin and independent of the rescaled Hamiltonian, while sΛ(ε) is the system-specific Boltzmann entropy per particle, i.e. –sΛ(ε) is the minimum of Boltzmann's H function for a perfect gas of energy ε subjected to a combination of externally and self-generated fields. It is also shown that any limit point of the n-point marginal ensemble measures is a linear convex superposition of n-fold products of the H-function-minimizing one-point functions. The proofs are direct, in the sense that (a) the map [Formula: see text] is studied rather than its inverse [Formula: see text]; (b) no regularization of the microcanonical measure [Formula: see text] is invoked, and (c) no detour via the canonical ensemble. The proofs hold irrespective of whether microcanonical and canonical ensembles are equivalent or not.
Publisher
World Scientific Pub Co Pte Lt
Subject
Mathematical Physics,Statistical and Nonlinear Physics
Cited by
13 articles.
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