Studies on growth and characterization of a nonlinear optical crystal: Zinc sulfate-doped L-alanine

Author:

Thangavel S.1,Kathiravan V.2,Ashok Kumar R.1,Eniya S.2,Satheesh Kumar G.3,Selvarajan P.4,Kumaresavanji M.3

Affiliation:

1. PG and Research Department of Physics, Thiruvalluvar Government Arts College, Rasipuram 01, Tamilnadu, India

2. Crystal Growth Laboratory, PG and Research Department of Physics, Government Arts College (Autonomous), Karur 05, Tamilnadu, India

3. Crystal Growth Laboratory, PG and Research Department of Physics, National College (Autonomous), Tiruchirappalli 01, Tamilnadu, India

4. Department of Physics, Aditanar College of Arts and Science, Tiruchendur 628 216, Tamilnadu, India

Abstract

Single crystals of zinc sulfate doped L-alanine (LAZ) were grown by adopting the slow evaporation technique at room temperature. The crystal structure of LAZ was determined using single-crystal X-ray diffraction. The functional groups of LAZ were identified by FT-IR spectroscopy analysis. UV–Visible–NIR transmittance study was carried out, and the bandgap energy was found. A fluorescence study was performed to get the emission spectrum of the LAZ crystal. The Vickers microhardness test is used to determine the LAZ crystals mechanical behavior. Thermogravimetric and differential thermal analyses have also been studied to investigate the thermal property of the LAZ crystal. The efficiency of the title crystal’s second harmonic generation (SHG) was investigated. The electrical properties were estimated by impedance study.

Publisher

World Scientific Pub Co Pte Ltd

Subject

Physics and Astronomy (miscellaneous),Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials

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