Investigation of nondegenerate two-photon absorption in common fluorescent dyes

Author:

Xu Huantian1,Chen Shu1,Mu Kaijun1,Wang Junqiao1,Tian Yongzhi1,Su Shilei1,Mao Yanchao1,Liang Erjun1

Affiliation:

1. School of Physics and Engineering and Key Laboratory of Materials, Physics of Ministry of Education of China, Zhengzhou University, Zhengzhou 450001, P. R. China

Abstract

The nondegenerate two-photon excited fluorescence (ND-TPEF) and nondegenerate two-photon absorption (ND-TPA) cross-sections of two common fluorescent dyes were investigated using the femtosecond pump-probe technique at several wavelength combinations. Time-resolved and laser intensity dependent fluorescence revealed that the fluorescence was originated from the ND-TPA effect. Experimental ND-TPA cross-section exhibited larger values than corresponding degenerate two-photon absorption case. Additionally, an improved essential-state model involving multiple TPA excited states was proposed to evaluate the TPA cross-section of organic molecules, which showed good agreement with experimental results. This study indicates that the investigated fluorescent dyes would play important roles in multicolor two-photon imaging.

Publisher

World Scientific Pub Co Pte Lt

Subject

Physics and Astronomy (miscellaneous),Atomic and Molecular Physics, and Optics,Electronic, Optical and Magnetic Materials

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