Recent developments in the coordination chemistry of porphyrin complexes containing non-metallic and semi-metallic elements

Author:

Brothers Penelope J.1

Affiliation:

1. Department of Chemistry, The University of Auckland, Private Bag 92019, Auckland, New Zealand

Abstract

Recent advances in the chemistry of main group porphyrin complexes are surveyed. New, unprecedented structural types for porphyrin complexes which have been revealed from the recent reports of boron and tellurium porphyrins are described. Advances in the preparation and reactivity of Group 14 (silicon and tin) and Group 15 porphyrin complexes are discussed. A systematic variation in the out-of-plane distortion (ruffling) of light element Group 14 and 15 porphyrin complexes has become apparent now that a significant number of structurally characterized examples are at hand.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Reference33 articles.

1. J. K. M. Sanders, The Porphyrin Handbook 3, eds. K. M. Kadish, K. M. Smith and R. Guilard (Academic Press, San Diego, 1999) pp. 1–48.

2. W. R. Scheidt, The Porphyrin Handbook 3, eds. K. M. Kadish, K. M. Smith and R. Guilard (Academic Press, San Diego, 1999) pp. 49–112.

3. New Coordination Mode for the Porphyrin Ligand in the Boron Porphyrin Complex B2OF2(TTP)

4. Coordinated B2 Bridges in Porphyrins-Unexpected Formation of a Diborane(4)- from a Diborylporphyrin

5. Novel Coordination in the First Tellurium Porphyrin Complex: Synthesis and Crystal Structure of [Te(ttp)Cl2]

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