Synthesis of unusual phthalocyanines and naphthalocyanines

Author:

Hanack Michael1,Iqbal Zafar1,Lyubimtsev Alexey2,Özcesmeci Ibrahim1,Özcesmeci Mukaddes1,Ziegler Thomas1

Affiliation:

1. Institut für Organische Chemie der Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany

2. Ivanovo State University of Chemistry and Technology, Organic Chemistry Department, F. Engels Str. 7, 153460 Ivanovo, Russia

Abstract

This paper is a summary of the lecture Michael Hanack gave at the 5th ICPP meeting in Moscow. A new method for the preparation of phthalonitriles is reported which makes the syntheses of substituted phthalocyanines much easier. Then the generation of highly reactive dehydrophthalocyanines using different methods is described. The reaction of these intermediates with dienophiles and various solvents is also discussed. In the last section, the syntheses of tetra- and octa- Zn phthalocyanine and -naphthalocyanine carbohydrate conjugates, which will be used for photosensitizers in PDT, is reported.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

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