Photodegradation of organic pollutants in water by immobilized porphyrins and phthalocyanines

Author:

Fernández Lucía123,Esteves Valdemar I.2,Cunha Ângela3,Schneider Rudolf J.4,Tomé João P.C.156

Affiliation:

1. QOPNA, and Department of Chemistry, University of Aveiro, Aveiro, 3810-193, Portugal

2. CESAM and Department of Chemistry, University of Aveiro, Aveiro, 3810-193, Portugal

3. Department of Biology & CESAM, University of Aveiro, Aveiro, 3810-193, Portugal

4. BAM Federal Institute for Materials Research and Testing, Berlin, D-12205, Germany

5. Centro de Química Estrutural, Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001, Lisboa, Portugal

6. Department of Organic and Macromolecular Chemistry, Ghent University, Gent, B-9000, Belgium

Abstract

New methods for water treatment are required as a result from an increasing awareness in the reduction of the pollution impact in the environment. In the perspective of the photo-oxidation of organic pollutants present in water, the principal incentive for the preparation of heterogeneous photocatalysts is their easy recovery from the reaction mixture, which allows their reuse in successive runs, minimizing the loss of their original photocatalytic properties. Different types of supports can be used in the immobilization of photoactive species, such as porphyrins (Pors) and phthalocyanines (Pcs). This mini-review will consider the different methodologies for the immobilization of Pors and Pcs and their photocatalytic performance in the photodegradation of organic pollutants in water, addressing also their recycling ability in successive water treatments.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

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