Affiliation:
1. Department of chemistry, University of Akron, Akron, OH 44325-3601, USA
Abstract
Two high resolution single X-ray crystal structures of meso-substituted free-base corroles are presented: 5,10,15-triphenylcorrole (1) and 5,10,15-tris(pentafluorophenyl)corrole (2). The internal NH protons are clearly assignable to different nitrogens, which represents the two tautomer limits of corrole.
Publisher
World Scientific Pub Co Pte Lt
Reference17 articles.
1. R. Paolesse, The Porphyrin Handbook 2, eds. K. M. Kadish, K. M. Smith and R. Guilard (Academic Press, San Diego, 2000) pp. 201–232.
2. C. Erben, S. Will and K. M. Kadish, The Porphyrin Handbook 2, eds. K. M. Kadish, K. M. Smith and R. Guilard (Academic Press, San Diego, 2000) pp. 233–300.
3. Synthesis and Characterization of Germanium, Tin, Phosphorus, Iron, and Rhodium Complexes of Tris(pentafluorophenyl)corrole, and the Utilization of the Iron and Rhodium Corroles as Cyclopropanation Catalysts
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