π-Conjugated multiporphyrin box via self-assembly of an ethynylene-bridged zinc porphyrin dimer-Reference-Cited by-同舟云学术

π-Conjugated multiporphyrin box via self-assembly of an ethynylene-bridged zinc porphyrin dimer

Published:2003-05 Issue:05 Volume:07 Page:388-393
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Tsuda Akihiko¹,Hu Haifeng¹,Watanabe Reiko¹,Aida Takuzo¹

Affiliation:

1. Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan

Abstract

An ethynylene-bridged zinc porphyrin dimer bearing metal-coordinating groups, such as bis[{5-(4-pyridyl)-15-(3,5-didodecyloxyphenyl)porphyrinato}zinc] Z2, self-assembles in CHCl 3 to form a rectangular-shaped supramolecular nano box, in which all the Z2 units preferentially adopt a planar conformation with a syn-parallel geometry as for the pyridyl groups.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424603000501

Reference9 articles.

1. Supramolecular Assemblies between Macrocyclic Porphyrin Hexamers and Star-Shaped Porphyrin Arrays

2. A Self-Assembled Porphyrin Box from mesomeso-Linked Bis{5-p-pyridyl-15-(3,5-di-octyloxyphenyl)porphyrinato zinc(II)}

3. Highly Conjugated, Acetylenyl Bridged Porphyrins: New Models for Light-Harvesting Antenna Systems

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