Preparation and characterization of meso-tetrakis(2,6-diaryloxyphenyl)porphyrins-Reference-Cited by-同舟云学术

Preparation and characterization of meso-tetrakis(2,6-diaryloxyphenyl)porphyrins

Published:2006-02 Issue:02 Volume:10 Page:104-116
ISSN:1088-4246
Container-title:Journal of Porphyrins and Phthalocyanines
language:en
Short-container-title:J. Porphyrins Phthalocyanines

Author:

Tohara Akira¹,Sugawara Yoko²,Sato Mitsuo¹

Affiliation:

1. Biophysics Division, Faculty of Pharmaceutical Sciences, Teikyo University, Suwarashi, Sagamikomachi, Sagamihara, Kanagawa 199-0106, Japan

2. Department of Physics, School of Science, Kitasato University, Kitasato, Sagamihara, Kanagawa 228-8555, Japan

Abstract

A series of meso-tetrakis(2,6-diaryloxyphenyl)porphyrins was synthesized by the Lindsey method from pyrrole and 2,6-diaryloxybenzaldehydes, which were prepared by regioselective formylation of 1,3-diaryloxybenzenes. In CDCl 3 solution, 1 H NMR spectral analysis of ring current shifts arising from the porphyrin macrocycle and the attached phenyl rings indicated that meso-tetrakis(2,6-diphenoxyphenyl)porphyrin, the prototypical meso-tetrakis(2,6-diaryloxyphenyl)porphyrin, forms deep open well cavities above and below the porphyrin plane.

Publisher

World Scientific Pub Co Pte Lt

Subject

General Chemistry

Link

https://www.worldscientific.com/doi/pdf/10.1142/S1088424606000132

Reference37 articles.

1. Dioxygen Reactivity of Fully Reduced [LFeII···CuI]+ Complexes Utilizing Tethered Tetraarylporphyrinates: Active Site Models for Heme-Copper Oxidases

2. Dioxygen Reactivity of Reduced Heme and Heme−Copper Complexes Utilizing Tetraarylporphyrinates Tethered with Both a Pyridyl Axial Ligand and N,N-Bis[2-(2-pyridyl)ethyl]amine Chelate

3. Further synthetic and structural investigations of new pre-organized picket porphyrins

4. Synthesis, structure and properties of ferrocene functionalized porphyrins

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