Affiliation:
1. Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK
Abstract
The adsorption of methanol on clean and oxygen-precovered Ag{111} has been investigated by high-resolution infrared spectroscopy. On the clean surface a highly inclined, associatively adsorbed methanol overlayer was detected. The presence of coadsorbed atomic oxygen results in the formation of a surface methoxy species, which is shown to have its C-O bond axis oriented normal to the surface by the application of the metal-surface selection rule.
Publisher
World Scientific Pub Co Pte Lt
Subject
Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics
Cited by
6 articles.
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