An ISS Study of Ga-Dimer Arrangement in the GaP(001)-(4 × 2) Surface

Author:

Oishi N.1,Shoji F.2,Konishi A.3,Naitoh M.3,Nishigaki S.3

Affiliation:

1. Kumamoto National College of Technology, Kumamoto 861-11, Japan

2. Kyushu Kyoritsu University, Yahatanishi, Kitakyushu 807, Japan

3. Kyushu Institute of Technology, Tobata, Kitakyushu 804, Japan

Abstract

A GaP(001) Ga-rich surface produced by ion sputtering followed by annealing exhibited a 4 × 2 LEED pattern with half streaks in the [110] direction. We have studied the structure of this surface by low-energy ion-scattering spectroscopy (ISS) using alkali ions ( Na +) .We have found a unit cell of the 4 × 2 structure consisting of two Ga dimers plus two dimer vacancies from the measured incidence-angle dependence of the scattered-ion intensity in the [Formula: see text] surface azimuth and an atomic separation in the Ga dimer being about 0.27 nm from that in the [110] surface azimuth. Evidence is presented showing the unit structures being arranged irregularly in the [Formula: see text] direction around the twofold positions.

Publisher

World Scientific Pub Co Pte Lt

Subject

Materials Chemistry,Surfaces, Coatings and Films,Surfaces and Interfaces,Condensed Matter Physics

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