COMBINED STM AND RBS INVESTIGATION OF THE NUCLEATION AND GROWTH OF Au ON Ni(110): ALLOYING AND DEALLOYING

Abstract

We have performed in-situ Scanning Tunneling Microscopy (STM) and Rutherford Backscattering Spectroscopy (RBS) investigations of the room-temperature (RT) growth of Au on Ni(110) . At low coverages, we observe the formation of a Au/Ni surface alloy, even though Au is immiscible with bulk Ni at RT. At a critical Au coverage of θ Au = 0.4 ML (monolayer), we observe a “dealloying” phase transition where 0.16 ML of Au is “popping” out of the alloyed surface layer and nucleates into [001]-directed dimer/trimer Au chains. Increasing the Au coverage further causes the nucleation and growth of more [001]-directed chains, i.e. their mutual distance in the [Formula: see text] direction decreases until the chain structure finally saturates in a p(5 × 3) structure at θ Au = 0.93 ML . The formation of a surface alloy at low coverage is supported by theoretical calculations within the Effective-Medium Theory (EMT), and an atomic model for the [001]-directed Au chains is developed from a detailed interplay between experiments and theoretical calculations.