MAGNETIC AND STRUCTURAL PROPERTIES OF SCANDIUM CHALCOGENIDE SPINELS WITH IRON AND MANGANESE

Author:

PAWLAK LUCJAN1,DUCZMAL MAREK1

Affiliation:

1. Institute of Inorganic Chemistry and Metallurgy of Rare Elements, Technical University of Wroclaw, Wybrzeże Wyspiańskiego 27, 50–370 Wroclaw, Poland

Abstract

FeSc2S4, MnSc2S4 and MnSc2Se4 crystallize in the normal spinel structure. None of them orders magnetically above 4.2 K contrary to FeLu2S4, which orders at 8 K. This difference is discussed as being strongly dependent on the transfer of divalent iron to the octahedral sites and not on the interionic distances.

Publisher

World Scientific Pub Co Pte Lt

Subject

Condensed Matter Physics,Statistical and Nonlinear Physics

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