Affiliation:
1. Department of Physical Chemistry, Indian Association for the Cultivation of Science, Calcutta 700 032, India
Abstract
We present here a succinct account of the finite-temperature generalisation of the coupled cluster (CC) method. It requires the concept of thermal normal ordered products whose Boltzmann trace is zero. The basic idea is to express the Boltzmann operator as a normal ordered exponential containing cluster operators and a number, and express the free energy as a logarithm of a suitable Boltzmann trace, where only the number part in the ordered exponential survives. The free energy is manifestly extensive. Free energies of Lipkin model and anharmonic oscillators obtained from the grand partition function are discussed as example applications.
Publisher
World Scientific Pub Co Pte Lt
Subject
Condensed Matter Physics,Statistical and Nonlinear Physics
Cited by
17 articles.
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