FERROMAGNETIC TDAE-C60 VERSUS PARAMAGNETIC TDAE-C70: FARADEY BALANCE AND ESR STUDY

Author:

Tanaka Kazuyoshi1,Zakhidov Anvar A.1,Yoshizawa Kazunari1,Okahara Kenji1,Yamabe Tokio1,Yakushi Kyuya2,Kikuchi Koichi3,Suzuki Shinzo3,Ikemoto Isao3,Achiba Yohji3

Affiliation:

1. Department of Hydrocarbon Chemistry and Division of Molecular Engineering, Faculty of Engineering, Kyoto University, Kyoto, 606–01, Japan

2. Institute for Molecular Science, Myodaiji, Okazaki, 444, Japan

3. Department of Chemistry, Tokyo Metropolitan University, Hachi-oji, Tokyo, 192–03, Japan

Abstract

Magnetic properties of C 60 and C 70 complexes with tetrakis(dimethylamino)ethylene (TDAE) have been studied based on the measurements of the Faraday-balance magnetization and the electron spin resonance (ESR). It has been found that both TDAE- C 60 and TDAE- C 70 possess about one radical spin per fullerene molecule. TDAE- C 60 has been confirmed to show ferromagnetic-type transition at Tc=16.7–17.5 K . Appearance of a new broad and intense ESR signal below Tc of TDAE- C 60 suggests that the radical spins in the magnetically ordered state rather localize on each C 60 molecule and are ferromagnetically correlated. On the other hand, TDAE- C 70 does not show ferromagnetism in all the temperature range down to 4.5K.

Publisher

World Scientific Pub Co Pte Lt

Subject

Condensed Matter Physics,Statistical and Nonlinear Physics

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1. The Jahn–Teller Effect and Fullerene Ferromagnets;Fullerene-Based Materials;2004-03-19

2. Ferromagnetism in Metallocene-Doped Fullerenes;Monatshefte f�r Chemie / Chemical Monthly;2003-01-01

3. Magnetic properties of TDAE-C60 single crystal and powder samples: The influence of thermal annealing;Solid State Communications;1997-02

4. Irreversible and time-dependent magnetization in TDAE-C60;Solid State Communications;1996-02

5. Magnetic Properties;Science of Fullerenes and Carbon Nanotubes;1996

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