Hydrogen production using aluminum-based materials prepared by mechanical milling

Abstract

Aluminum (Al)-based materials composited of different low melting point materials were prepared by mechanical ball-milling. Hydrogen production using these materials was investigated to help resolving the safety issues associated with the storage and transportation of hydrogen. The phase composition and microstructure of the Al-based composited materials were examined using X-ray diffraction (XRD) and scanning electron microscopy (SEM), respectively. As observed in this study, the addition of low melting point metals (such as Sn, Bi and In) helped to lower the initial Al-water reaction temperature and to increase the yield in the production of hydrogen. Samples of optimized compositions, Al–6% Sn–4% Bi and Al–6% Sn–4% In, were found to exhibit high hydrogen production yields of up to 448 and 515 mL, respectively. Meanwhile, their hydrogen generation rates were increased.