Melting curves of Cu, Pt, Pd and Au under high pressures

Abstract

Melting curves of Cu, Pt, Pd and Au were calculated via the molecular dynamics method in the temperature range of [Formula: see text]1000–5000 K. The simulation results were compared with the recent high pressure experimental data reported by Errandonea, and the obtained melting curves of Cu, Pt and Au were all in good agreement with his results. For Pd, there were some differences between the obtained melting curve and the experimental data and these differences increased with decreasing temperature to about 7 GPa at 2000 K. The effects of the interaction forces between metal atoms at high atomic densities on the pressure of the system were analyzed. It was found that the pressure in metals predominantly depends on the interaction forces between atoms at high atomic densities. In addition, expressions for melting pressure as a function of temperature have been obtained by fitting the simulation results.