Enhanced electrocatalytic hydrazine oxidation on MoS2-GO nanosheets

Author:

Tanwade Pratiksha D.1,Mulik Balaji B.1,Sathe Bhaskar R.1ORCID,Musmade B. B.2ORCID,Shinde Vinayak3ORCID,Furube Akihiro3ORCID,Koinkar Panakaj3ORCID

Affiliation:

1. Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431004, India

2. Department of Instrumentation Engineering, D. Y. Patil College of Engineering, Akurdi, Pune 411044, Maharashtra, India

3. Institute of Post-LED Photonics, and Graduate School of Technology, Industrial and Social Science, Tokushima University, Tokushima 770-8506, Japan

Abstract

Herein, we present a comprehensive study on electrochemical hydrazine oxidation using hybrid material, MoS2-GO (molybdenum disulfide-graphene oxide), as an efficient electrocatalyst fabricated using the simple chemical reduction method. The MoS2-GO hybrid material adopts a distinctive open flower-like morphology, as demonstrated by field emission scanning electron microscopy (FE-SEM). Asymmetric and uneven distribution is indicated by energy dispersive X-ray spectroscopy (EDS), while UV–Vis investigation displays shifts in peak positions and intensities, signifying the successful formation of the MoS2-GO composite. Further supporting the composite’s structure, X-ray diffraction (XRD) studies validate the hexagonal arrangement of MoS2 layers on the graphene oxide (GO) surface. Through a combination of material synthesis, characterizations, and electrochemical analyses, we demonstrate that the MoS2-GO hybrid exhibits a low overpotential ∼0.2[Formula: see text]V versus SCE. This outstanding electrocatalytic performance of MoS2-GO underscores its potential as a promising candidate for various electrochemical applications, especially those involving hydrazine-based reactions. GO was used as the supporter and promoter by improving the synergetic effect between MoS2 and GO toward the hydrazine oxidation reaction.

Funder

CSIR-HRDG

DST-SERB

Publisher

World Scientific Pub Co Pte Ltd

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