Effect of Nb2O5 Content on Microstructure and Dielectric Properties of Ba2-2xNa1-xNb5O15-5x/2 Ceramics

Author:

Wang Peng1,Lee Joon Hyung1,Kim Jeong Joo1,Cho Sang Hee1,Lee Hee Young2

Affiliation:

1. Department of Inorganic Materials Engineering, Kyungpook National University, Daegu 702-701, Korea

2. Department of Materials Science and Engineering, Yeungnam University, Gyungsan, Kyungpook 712-749, Korea

Abstract

The effect of Nb 2 O 5 content on the microstructure development and the dielectric characteristics of tungsten-bronze-structured polycrystalline Ba 2 Na 1 Nb 5 O 15 (BNN) ceramics was studied. The compositions of stoichiometry, Nb 2 O 5–deficient and Nb 2 O 5–excess BNN were prepared and sintered at 1250 °C for 2 h in oxygen. We report the development of second phases, microstructure and dielectric behavior of polycrystalline BNN ceramics, which was not reported ever. The Nb 2 O 5 content affect lattice constant of the sintered body, which contributed to the change of phase transformation temperature. The stoichiometric BNN showed the lowest densification, while an optically transparent sample was obtained in Nb 2 O 5–excess highly dense sample.

Publisher

World Scientific Pub Co Pte Lt

Subject

Condensed Matter Physics,Statistical and Nonlinear Physics

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