Facile synthesis of highly macroporous Gum Arabic hydrophilic cryogel for dyes adsorption

Author:

Rehman Shams Ur1,Farooq Muhammad2,Haleem Abdul13ORCID,Ambreen Jaweria4,Siddiq Muhammad1,Althobaiti Saja Abdulrahman5

Affiliation:

1. Department of Chemistry, Quaid-i-Azam University, Islamabad, 45320, Pakistan

2. Department of Chemistry, Pakistan Institute of Engineering and Applied Sciences (PIEAS), Islamabad, 45650, Pakistan

3. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, P. R. China

4. Department of Chemistry, COMSATS University Islamabad, Park road 45550, Islamabad, Pakistan

5. Department of Chemistry, College of Art and Science, Prince Sattam Bin Abdulaziz University, Wadi Addawasir 18510, Saudi Arabia

Abstract

Porous materials are promising candidates for the removal of organic pollutants from different water bodies. Among porous materials, cryogels are more attractive candidates due to their macro-porosity and rapid adsorption. This work evaluated the fabrication and adsorption capability of macro-porous Gum Arabic-based Cryogel. The fabricated Gum Arabic cryogel was modified and protonated to the protonated modified Gum Arabic Cryogel to compare its adsorption capacities for three different dyes. The successful fabrication of cryogel was confirmed by Fourier Transform Infrared spectroscopy, Differential Scanning Calorimetry, Thermal gravimetric analysis and Scanning Electron Microscopy. The protonated modified Gum Arabic Cryogel showed enhanced adsorption capability towards subjected dyes by following second-order rate kinetics. These cryogels can be employed as an efficient adsorbent to remove toxic contaminants from wastewater effluents.

Publisher

World Scientific Pub Co Pte Ltd

Subject

Condensed Matter Physics,Statistical and Nonlinear Physics

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