PATH-INTEGRAL APPROACH TO A POLYMER CHAIN IN RANDOM MEDIA WITH LONG-RANGE DISORDER CORRELATIONS

Author:

KUNSOMBAT CHERDSAK1,SA-YAKANIT VIRULH2

Affiliation:

1. Department of Physics, Faculty of Science, Kasetsart University, Bangkok 10900, Thailand

2. Forum for Theoretical Science, Department of Physics, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand

Abstract

In this paper we consider the model of a flexible polymer chain embedded in a quenched random medium with long-range disorder correlations. Using the Feynman path integral approach we show that for the case of long-range quadratic correlations, we obtain an analytical result. The result is [Formula: see text], where 〈R2〉 is the mean square end-to-end distance of the polymer chain, ξ is the correlation length of disorder, Δ is an unknown parameter, b is the Kuhn step length, ρ is the density of random obstacles and N is the number of links. It is shown that for a polymer chain in a random media with long-range quadratic correlations, where ρ is not too high, the behavior of the polymer chain is like that of a free chain. This result agrees with the calculation using the replica method. However, in a medium where ρ is very high, the variation of the mean square end-to-end distance with disorder and its distance depending on ρ are found in our approach.

Publisher

World Scientific Pub Co Pte Lt

Subject

Condensed Matter Physics,Statistical and Nonlinear Physics

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