Affiliation:
1. School of Physics, Shandong University, Jinan 250100, P. R. China
Abstract
In this work, the nonadiabatic effects in the femtosecond photoionization of NaI molecule driven by pump and probe pulses are investigated theoretically using the accurate quantum wave packet method. The calculation with the inclusion of nonadiabatic coupling remarkably improves the agreement with experimental results of Jouvet et al. [J Phys Chen A101: 2555, 1997], indicating the importance of the nonadiabatic effect. Moreover, the dynamical evolutions of wave packets and their corresponding time-resolved photoelectron spectroscopy are presented both on the adiabatic and diabatic potentials. These comparisons contribute to further understanding of the influences of nonadiabatic effects in the femtosecond photoionization of NaI molecule.
Publisher
World Scientific Pub Co Pte Lt
Subject
Computational Theory and Mathematics,Physical and Theoretical Chemistry,Computer Science Applications
Cited by
10 articles.
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