Fast Synthesis of CHA-type Zeolite Using Dealuminated Amorphous Aluminosilicates with High Reactivity

Author:

Sada Yuki1,Miyagi Shoko2,Yoshioka Masato3,Ishikawa Tomoya3,Naraki Yusuke3,Sano Tsuneji2,Okubo Tatsuya1,Wakihara Toru12

Affiliation:

1. Department of Chemical System Engineering, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 , Japan

2. Institute of Engineering Innovation, School of Engineering, The University of Tokyo, 2-11-16 Yayoi, Bunkyo-ku, Tokyo 113-8656 , Japan

3. Inorganic Materials Research Laboratory, Tosoh Corporation, 4560 Kaiseicho, Shunan, Yamaguchi 746-8501 , Japan

Abstract

Abstract Use of dealuminated amorphous aluminosilicates (deAl-Amor) achieved faster synthesis of CHA-type zeolites compared with using conventional amorphous aluminosilicates (Amor). The deAl-Amor also expanded the synthesis window of reactant compositions. Moreover, there was a large difference in morphologies of solid products obtained during the crystallization process between deAl-Amor and Amor, suggesting the time gap in supplying aluminosilicate species contributing to the CHA crystal growth. These results indicate the high potential of deAl-Amor as starting materials for zeolite synthesis.

Publisher

Oxford University Press (OUP)

Subject

General Chemistry

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