Rates and Mechanism for the Solvolyses of 2,2-Dimethyl-2-sila-1-indanyl Bromide and α-Trialkylsilylbenzylp-Toluenesulfonates. α-Silicon Effect on the Stability of Benzylic Cations in Solution-Reference-Cited by-同舟云学术

Rates and Mechanism for the Solvolyses of 2,2-Dimethyl-2-sila-1-indanyl Bromide and α-Trialkylsilylbenzylp-Toluenesulfonates. α-Silicon Effect on the Stability of Benzylic Cations in Solution

Published:1991-04 Issue:4 Volume:64 Page:1145-1152
ISSN:0009-2673
Container-title:Bulletin of the Chemical Society of Japan
language:en
Short-container-title:BCSJ

Author:

Shimizu Nobujiro,Osajima Erika,Tsuno Yuho

Publisher

The Chemical Society of Japan

Subject

General Chemistry

Link

https://www.jstage.jst.go.jp/article/bcsj1926/64/4/64_4_1145/_pdf

Reference41 articles.

1. .gamma.-Silicon stabilization of carbonium ions in solvolysis. I. Solvolysis of cis- and trans-3-(trimethylsilyl)cyclohexyl p-bromobenzenesulfonates

2. Stabilization of positive charge by .beta.-silicon

3. Determination of the .beta.-silicon effect from a mass spectrometric study of the association of trimethylsilylium with alkenes

4. Ab initio investigations of the .beta.-silicon effect on alkyl and cyclopropyl carbenium ions and radicals

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