Alternative Mechanistic Scheme for Salt Effects on Solvolysis Reactions of Haloalkanes and Related Compounds in Binary DMSO/H2O Solvent Mixture
Author:
Affiliation:
1. Department of Chemistry, Faculty of Science, Kochi University
Publisher
The Chemical Society of Japan
Subject
General Chemistry
Link
http://www.journal.csj.jp/doi/pdf/10.1246/bcsj.20120115
Reference44 articles.
1. Reactions of the tri-p-anisylmethyl carbonium ion with nucleophiles
2. Specific salt effects upon the rates of SN1 solvolyses
3. Large salt effects and ion pairing in trifluoroacetolysis forming destabilized delocalized benzylic carbocations. Kinetic analysis of the Winstein special salt effect
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