Photoreaction of Methyl (p-Nitrophenyl)diazoacetate in the Presence of an Electron-Donating Amine: Evidence for Intermediacy of the Carbene Radical Anion-Reference-Cited by-同舟云学术

Photoreaction of Methyl (p-Nitrophenyl)diazoacetate in the Presence of an Electron-Donating Amine: Evidence for Intermediacy of the Carbene Radical Anion

Published:2000-11 Issue:11 Volume:29 Page:1282-1283
ISSN:0366-7022
Container-title:Chemistry Letters
language:en
Short-container-title:Chem. Lett.

Author:

Mizushima Tadashi,Ikeda Shingo,Murata Shigeru,Ishii Kunihiko,Hamaguchi Hiro-o

Publisher

The Chemical Society of Japan

Subject

General Chemistry

Reference16 articles.

1. Hypovalent radicals. 6. Electroreduction of diazodiphenylmethane - intermediacy of Ph2CN2-.cntdot. and Ph2C-.cntdot.

2. Kinetic evidence for the formation of the carbene anion radical (EtO2C)2C-.cntdot.

3. Generation of carbene anion radicals from diazo compounds. Factors influencing the unimolecular decomposition of the anion radicals of diazo compounds in solution

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