Estimation of the Compositional Proportions of Different Micelle Species in Water: Application of One-dimensional Aggregate Theory to Small Angle Neutron Scattering Analyzed Data

Author:

Okabayashi Hiro-Fumi1,Sasuga-Araki Sonoko1,Izawa Ken-Ichi2,O’Connor Charmian J3

Affiliation:

1. Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso, Showa-ku, Nagoya, Aichi 466-8555 , Japan

2. Research & Development Group, Fuji Silysia Chemical Ltd., 2-1846, Kozoji, Aichi 487-0013 , Japan

3. School of Chemical Science, The University of Auckland, Private Bag 92019, Auckland 1142, New Zealand

Abstract

Abstract The one-dimensional aggregation theory was applied to the small angle neutron scattering (SANS) analyzed data of surfactant solutions. Plots of the hydrophobic bonding energy E to form an aggregate against the number-average aggregation number n were found to be powerful to estimate the compositional ratios of different aggregate species co-existing in a gross sample solution.

Publisher

Oxford University Press (OUP)

Subject

General Chemistry

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