Intermediacy of Rapidly Equilibrating Classical Cations in the Solvolyses of 4-Methylene-2ax-adamantylp-Toluenesulfonate
Author:
Publisher
The Chemical Society of Japan
Subject
General Chemistry
Link
https://www.jstage.jst.go.jp/article/cl/22/11/22_11_1981/_pdf
Reference17 articles.
1. The SN2-SN1 spectrum. 1. Role of nucleophilic solvent assistance and nucleophilically solvated ion pair intermediates in solvolyses of primary and secondary arenesulfonates
2. The SN2-SN1 spectrum. 2. Quantitative treatments of nucleophilic solvent assistance. A scale of solvent nucleophilicities
3. An ab initio molecular orbital study of the 2-adamantyl cation
4. Geometric equivalents of enantiomers in studies of the stereochemical course of substitution at carbon. Electronic effects in nucleophilic addition to carbonyl groups and to carbocations. Virtual proof of the existence of .sigma. participation by unstrained carbon-carbon bonds
Cited by 6 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. ChemInform Abstract: Intermediacy of Rapidly Equilibrating Classical Cations in the Solvolyses of 4-Methylene-2ax-adamantyl p-Toluenesulfonate.;ChemInform;2010-08-19
2. Protonation studies on epimeric homoallylic adamantylideneadamantyl alcohols, 4-methyleneadamantylideneadamantane, adamantylideneadamantane (AdAd) and sesquihomoadamantene, and reaction of AdAd and sesquihomoadamantene with NO2+BF4– and PhI(OH)OTs: a stable-ion NMR and theoretical (GIAO-NMR) studyElectronic supplementary information (ESI) available: representative 1D-NMR spectra and tables of cartesian coordinates. See http://www.rsc.org/suppdata/p2/b2/b201660e/;Journal of the Chemical Society, Perkin Transactions 2;2002-04-17
3. An unstrained homoallylic secondary adamantyl toluene-p-sulfonate solvolyses with σ-bond migration to give a protoadamantyl substituted allylic carbenium ion;Journal of the Chemical Society, Perkin Transactions 2;1997
4. Synthesis of Bifunctional Polycyclic Compounds and Their Application to Mechanistic Studies of Solvolysis Reactions;Bulletin of the Chemical Society of Japan;1996-04
5. Solvolyses of 4-methylene-2ax- and -2eq-adamantylp-toluenesulphonates: Intermediacy of classical carbocation in the axial and ?-bridged carbocation in the equatorialptoluenesulphonate solvolyses;Journal of Physical Organic Chemistry;1994-08
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