An Interpretation of the Puzzling Dichotomy of the Reaction Modes Observed during the Side-chain Nitration of Alkylaromatics with HNO3/CH2Cl2and HNO3/(CH3CO)2O
Author:
Publisher
The Chemical Society of Japan
Subject
General Chemistry
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4. The Nitration of Acylpentamethylbenzenes and 1,3-Diacyltetramethylbenzenes Bearing, as the Acyl Components, Pivaloyl, Trichloroacetyl, and Tribromoacetyl Groups. Exclusive Attack on the Methyl Group at the Most Crowded Site
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1. Pentamethylphenyl (Ph*) ketones: Unique building blocks for organic synthesis;Tetrahedron Letters;2021-06
2. Thermal and Photochemical Decomposition Pathways of Trinitromethylarenes. Part I. The Conversion of ArC(NO2)3 to ArNO2 -- a Rationalization of Apparent Solvent Effects.;Acta Chemica Scandinavica;1996
3. Positional Reactivity of Acylpolymethylbenzenes in Electrophilic Substitution;Bulletin of the Chemical Society of Japan;1994-03
4. Electron-transfer mechanism for aromatic nitration via the photoactivation of EDA (electron donor-acceptor) complexes. Direct relationship to electrophilic aromatic substitution;Journal of the American Chemical Society;1993-04
5. Ortho-selective side-chain nitration of α-Bromoacylpolymethylbenzenes and its application to the syntheses of indan-1-one and inden-1-one derivatives;Tetrahedron;1993-01
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