Photocatalytic Dehydrogenation of N-Heterocycles Promoted by Radicals from Graphene Oxide-Reference-Cited by-同舟云学术

Photocatalytic Dehydrogenation of N-Heterocycles Promoted by Radicals from Graphene Oxide

Published:2023-05-19 Issue:6 Volume:96 Page:568-571
ISSN:0009-2673
Container-title:Bulletin of the Chemical Society of Japan
language:en
Short-container-title:

Author:

Ahmed Md Razu¹,Nishina Yuta¹²

Affiliation:

1. Graduate School of Natural Science & Technology, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530 , Japan

2. Research Core for Interdisciplinary Science, Okayama University, 3-1-1 Tsushimanaka, Kita-ku, Okayama 700-8530 , Japan

Abstract

Abstract Visible light-induced photocatalytic dehydrogenation of N-heterocycles was achieved by graphene oxide (GO). Unlike previously reported thermally induced GO-promoted reactions, this system generates radicals and molecular hydrogen, which are confirmed by electron spin resonance and gas chromatography. A metal-free, oxidant-free, and recyclable photocatalytic reaction were achieved by a carbon-based system for the first time.

Publisher

Oxford University Press (OUP)

Subject

General Chemistry

Link

https://academic.oup.com/bcsj/article-pdf/96/6/568/56318940/bcsj.20230059.pdf

Reference24 articles.

1. Ruthenium-Catalyzed Hydrative Cyclization of 1,5-Enynes

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