Syntheses of Chelating Agents. I. Stability of the Metal Chelate of Benzylamine-N,N-diacetic Acid and its Nitro Derivatives
Author:
Publisher
The Chemical Society of Japan
Subject
General Chemistry
Reference10 articles.
1. Stability of Metal Chelates. I. Iminodiacetic and Iminodipropionic Acids
2. Stability of Metal Chelates. II. β-Hydroxyethyliminodiacetic Acid
3. Komplexone III1. Uramil-diessigsäure und ihr Komplexbildungsvermögen
4. Komplexone IV. Die Acidität und die Erdalkalikomplexe der Anilin-diessigsäure und ihrer Substitutionsprodukte
5. Komplexone XIX. Die Bildungskonstanten von Schwer-metallkomplexen der Nitrilo-triessigsäure
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1. Dense Monolayers of Metal-Chelating Ligands Covalently Attached to Carbon Electrodes Electrochemically and Their Useful Application in Affinity Binding of Histidine-Tagged Proteins;Langmuir;2005-03-12
2. Chiral Separation of Carboxymethyl Derivatives of Amines by Liquid Chromatography on Reversed-phase Silica Gel Coated with N-n-Dodecyl-L-hydroxyproline;Journal of High Resolution Chromatography;1999-09-01
3. 1,2‐FDTA: A Ferrocene‐Based Redox‐Active EDTA Analogue with a High Ca 2+ /Mg 2+ and Ca 2+ /Sr 2+ Selectivity in Aqueous Solution;Chemische Berichte;1997-10
4. FDTA [1,1′‐ F errocendiyl d i(methyleneamino) t etra a cetate] – An Organometallic Relative of EDTA The tetrasodium salt of 1,1′‐ f errocendiyl d i(methyleneamino)‐ t etra a cetate (FDTA‐Na 4 ) – a relative of EDTA (ethylene d i‐amino t etra a cetate) – was prepared from the reaction of N,N′ ‐1,1′‐ferrocendiylbismethylenebis(pyridinium) chloride tosylate with tetramethyl iminodiacetate and subsequent saponification with NaOH/CH 3 OH. Potentiometric titrations were performed to determine the stability constants of the complexes of FDTA (= L) with the alkaline earth metal ions Mg 2+ , Ca 2+ , Sr 2+ , and Ba 2+ (β: brutto stability constants): MgL (log β = 4.63), MgL 2 (log β = 8.10), CaL (log β = 4.97), CaLH (log β = 14.20); SrL (log β = 3.91), SrLH (log β = 13.43), and BaL (log β = 3.06). The stability constants are discussed with a view to cooperative effects of the two iminodiacetate groups in FDTA. The nonexistence of M 2 L and ML 2 (M = Ca, Sr) species is considered indicative of a cooperative effect of the donor groups. The X‐ray crystal structure of FDTA‐Na 4 was determined.;Chemische Berichte;1993-12
5. Adsorption of nitrogen monoxide by the chelate resin-immobilized iron(II) complex and its application for simultaneous removal of nitrogen monoxide and sulfur dioxide;Industrial & Engineering Chemistry Research;1990-11
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