Silane(silyl) and Bis(silyl)hydrido Manganese Complexes with Different Mn···H···Si Interaction: Observation of Gradual Si–H Bond Activation on the Metal Center
Author:
Affiliation:
1. Department of Chemistry, Graduate School of Science, Tohoku University
Publisher
The Chemical Society of Japan
Subject
General Chemistry
Link
http://www.journal.csj.jp/doi/pdf/10.1246/cl.2012.774
Reference15 articles.
1. Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products
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3. The σ-CAM Mechanism: σ Complexes as the Basis of σ-Bond Metathesis at Late-Transition-Metal Centers
4. Synthesis and characterisation of hydrido molybdenum and tungsten complexes having a hemilabile tridentate Si,Si,O-ligand: observation of stepwise hydrosilylation of a nitrile to form an N-silylimine on the metal centre
5. Covalent radii revisited
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