Orbital Tilting and Hybridization Change. An Illustrational Molecular Orbital Approach to an Addition (CH2=CH2+HBr→CH3CH2Br) and an Elimination Reaction (CH3CH2Br/Base→CH2=CH2)-Reference-Cited by-同舟云学术

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Orbital Tilting and Hybridization Change. An Illustrational Molecular Orbital Approach to an Addition (CH2=CH2+HBr→CH3CH2Br) and an Elimination Reaction (CH3CH2Br/Base→CH2=CH2)

Published:1990-10 Issue:10 Volume:63 Page:2850-2856
ISSN:0009-2673
Container-title:Bulletin of the Chemical Society of Japan
language:en
Short-container-title:BCSJ

Author:

Ito Suketaka,Kakehi Akikazu

Publisher

The Chemical Society of Japan

Subject

General Chemistry

Link

https://www.jstage.jst.go.jp/article/bcsj1926/63/10/63_10_2850/_pdf

Reference27 articles.

1. Recognition of stereochemical paths by orbital interaction

2. Sigma-Pi Interaction Accompanied by Stereoselection

3. The Stereoselection Rule for Electrocyclic Interactions

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1. Electrophilic Additions to Double Bonds;PATAI'S Chemistry of Functional Groups;2009-12-15

2. Correlation between the experimental and calculated (COSMO-AM1) activation free enthalpy of the hydroxide-induced elimination reaction of small haloalkanes in water;Journal of Molecular Structure: THEOCHEM;2000-06

3. Theoretical investigation on base-induced 1,2-eliminations in the model system fluoride ion + fluoroethane. The role of the base as a catalyst;Journal of the American Chemical Society;1993-10

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