Analysis of Solvent Effects on the Rate of the Cope Rearrangement: Evidence for Its Hydrogen-Bond-Insusceptible Nature
Author:
Publisher
The Chemical Society of Japan
Subject
General Chemistry
Link
https://www.jstage.jst.go.jp/article/bcsj1926/63/2/63_2_643/_pdf
Reference10 articles.
1. Facile heterolysis of a carbon-carbon bond. Arylazodicyanomethanides as the leaving group capable of generating tert-cumyl cation and the hydrogen-bond-insusceptible behavior of the leaving group anions
2. Azo Cope rearrangement. A sigmatropic change having a strong bias in the direction of heterolytic bond cleavage
3. Rearrangement of Allylic Thiobenzoates
4. The Rearrangement of Allyl Groups in Three-Carbon Systems. I.1
5. Activation Energies and Entropies of Activation in the Rearrangement of Allyl Groups in Three Carbon Systems1
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1. Two-directional carbon chain elongation via the consecutive 1,4-addition of allyl malononitrile and the Cope rearrangement on an alkynoate platform;Tetrahedron Letters;2016-01
2. References;Solvents and Solvent Effects in Organic Chemistry;2010-11-26
3. Lösungsmitteleffekte auf das Gleichgewicht zwischen lokalisierten und delokalisierten Zuständen thermochromer Semibullvalene und Barbaralane;Angewandte Chemie;1999-04-19
4. Quantitative Analysis of Solvent Effects on the Rate of Heterolysis Reactions: Relative Importance of Cation and Anion Solvation;Bulletin of the Chemical Society of Japan;1994-03
5. Facile Carbon–Carbon Bond Heterolysis.SN1–E1 Reactions oft-Cumyl andt-Butyl Substituted Tricyanomethanes;Chemistry Letters;1990-05
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