Stereoselective Synthesis of (2E,4E)- and (2Z,4E)-2,4-Alkadienoates by the Ester Enolate Claisen Rearrangement of (E)-1-Alkyl-3-trimethylsilyl-2-propenyl Glycolates Followed by the Peterson Reaction-Reference-Cited by-同舟云学术

Stereoselective Synthesis of (2E,4E)- and (2Z,4E)-2,4-Alkadienoates by the Ester Enolate Claisen Rearrangement of (E)-1-Alkyl-3-trimethylsilyl-2-propenyl Glycolates Followed by the Peterson Reaction

Published:1986-09-05 Issue:9 Volume:15 Page:1553-1556
ISSN:0366-7022
Container-title:Chemistry Letters
language:en
Short-container-title:Chem. Lett.

Author:

Sato Toshio,Tsunekawa Hiroshi,Kohama Hiromasa,Fujisawa Tamotsu

Publisher

The Chemical Society of Japan

Subject

General Chemistry

Reference25 articles.

1. A new alkamide from Piper sylvaticum

2. A novel five-carbon homologation leading to 3,4-alkadienoic acids by SN2′ reaction of β-ethynyl-β-propiolactone with grignard reagents in the presence of copper(i) catalyst

3. Highly stereoselective synthesis of (2E,4E)-dienamides and (2E,4E)-dienoates via a double elimination reaction

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