RhCl(PPh3)3/NaI Catalyst System for Hydrosilylation of 1-Alkynes: Stereodivergent Syntheses of E- and Z-Alkenylsilanes with Heteroatom Substituents on Silicon
Author:
Publisher
The Chemical Society of Japan
Subject
General Chemistry
Link
https://www.jstage.jst.go.jp/article/cl/27/5/27_5_443/_pdf
Reference14 articles.
1. Organofluorosilicates in organic synthesis. 1. A novel general and practical method for anti-Markownikoff hydrohalogenation of olefins via organopentafluorosilicates derived from hydrosilylation products
2. Silafunctional compounds in organic synthesis. Part 20. Hydrogen peroxide oxidation of the silicon-carbon bond in organoalkoxysilanes
3. Palladium-catalyzed cross-coupling reaction of organometalloids through activation with fluoride ion
4. A convenient and novel route to bis(.eta.-alkyne)platinum(0) and other platinum(0) complexes from Speier's hydrosilylation catalyst H2[PtCl6].xH2O. X-ray structure of [Pt{(.eta.-CH2=CHSiMe2)2O}(P-t-Bu3)]
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1. Regio- and stereoselective hydrosilylation of alkynes with alkoxysilanes for the synthesis of β-(Z) vinylsilanes catalyzed by a dirhodium(ii)/XantPhos complex;Organic Chemistry Frontiers;2024
2. Rh(I)/(III)‐N‐Heterocyclic Carbene Complexes: Effect of Steric Confinement Upon Immobilization on Regio‐ and Stereoselectivity in the Hydrosilylation of Alkynes;Chemistry – A European Journal;2021-11-08
3. Transition-Metal-Catalyzed Stereo- and Regioselective Hydrosilylation of Unsymmetrical Alkynes;Synthesis;2021-08-23
4. Short-Chained Platinum Complex Catalyzed Hydrosilylation under Thermomorphic Conditions: Heterogeneous Phase Separation at Ice Temperature;Molecules;2021-01-13
5. Stereodivergent Catalysis;Chemical Reviews;2018-04-20
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