Diastereoselective Introduction of an Allyl Group to the α′-Position of α-Substituted Pyrrolidines through the Intermediate Formation ofN-Acyliminium Ions-Reference-Cited by-同舟云学术

Diastereoselective Introduction of an Allyl Group to the α′-Position of α-Substituted Pyrrolidines through the Intermediate Formation ofN-Acyliminium Ions

Published:1991-01 Issue:1 Volume:20 Page:81-84
ISSN:0366-7022
Container-title:Chemistry Letters
language:en
Short-container-title:Chem. Lett.

Author:

Shono Tatsuya,Fujita Tetsuhiro,Matsumura Yoshihiro

Publisher

The Chemical Society of Japan

Subject

General Chemistry

Link

https://www.jstage.jst.go.jp/article/cl/20/1/20_1_81/_pdf

Reference5 articles.

1. Chemoenzymatic preparation of trans-2,6-dialkylpiperidines and of other azacycle building blocks. Total synthesis of (+)-desoxoprosopinine

2. The addition of alkylzinc iodides to 1-(phenoxycarbonyl)-2,3-dihydropyridinium salts. A synthesis of 2-alkyl-Δ3-piperidines.

3. Highly stereoselective addition of alkylcopper reagents to n-acyliminium ions. Enantioselective synthesis of trans-2- butyl-5-heptylpyrrolidine.

4. Synthesis of optically active piperidine and pyrrolidine alkaloids from L-lysine, L-ornithine, or L-proline using anodic oxidation as key steps

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