Affiliation:
1. University of Cambridge
2. Diamond Light Source
3. Rutherford Appleton Laboratory
4. university of oxford
Abstract
Four novel dicyanamide-containing hybrid organic-inorganic ABX3 structures are reported, and the thermal behaviour of a series of nine perovskite and non-perovskite ABX3 structures in total are analysed. Structure-property relationships are investigated by varying both A-site organic and B-site transition metal cations. The introduction of larger tetraalkylammonium cations into the A-site reduces the melting temperature, and raises the Tolerance Factor. Total scattering methods are used to provide a greater understanding of the melting mechanism.
Publisher
Cambridge University Press (CUP)
Cited by
1 articles.
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