Studies on the Thermodynamic and Kinetic Properties of Reactions of Bo(Bs) with H2-Reference-Cited by-同舟云学术

Studies on the Thermodynamic and Kinetic Properties of Reactions of Bo(Bs) with H2

Published:2006-01 Issue:1 Volume:31 Page:1-9
ISSN:1468-6783
Container-title:Progress in Reaction Kinetics and Mechanism
language:en
Short-container-title:Progress in Reaction Kinetics and Mechanism

Author:

Yin Ping¹,Hu Yucai¹,Zheng Hegen²,Du Qingjun¹,Liu Bing¹,Jiang Wei¹

Affiliation:

1. School of Chemistry and Materials Science, Ludong University, Yantai 264025, P.R. China

2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P.R. China

Abstract

The thermodynamic and kinetic properties of reactions of BO (BS) with H2 have been investigated within the temperature range of 200 – 1200 K using general statistical thermodynamics and transition state theory with the Wigner correction. It is concluded that the orders of their equilibrium constants and reaction rate constants are similar, especially at high temperature. Moreover, reaction 2 and reaction 4 have both thermodynamic and kinetic advantages over the whole temperature range for the BO=H2 and BS=H2 system, respectively.

Publisher

SAGE Publications

Subject

Physical and Theoretical Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/007967406779133966

Reference9 articles.

1. Gasification of Boron Oxide Drops in Combustion Gases

2. Gas-phase modeling of homogeneous boron/oxygen/hydrogen/carbon combustion

3. Kinetic model for hydrocarbon-assisted particulate boron combustion

4. Kinetics of high-temperature B/O/H/C chemistry

5. B(2P)+ H2O (X1A1): a quasi-classical 3D trajectory calculation

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