Mechanism and Phenomenology of an Oscillating Chemical Reaction

Author:

Taylor Annette F.1

Affiliation:

1. University of Leeds, Department of Chemistry, Leeds, LS2 9JT, UK.

Abstract

Chemical reactions, which are far from equilibrium, are capable of displaying oscillations in species concentrations and hence in colour, electrode potential, pH and/or temperature. The oscillations arise from the interplay between positive and negative kinetic feedback. Mechanisms for such reactions are presented, along with the rich phenomenology that these systems exhibit, from complex oscillations and chemical waves, to stationary concentration patterns. This review will focus on the Belousov-Zhabotinksy reaction but reference to other reactions will be made where appropriate.

Publisher

SAGE Publications

Subject

Physical and Theoretical Chemistry

Reference357 articles.

1. An Introduction to Nonlinear Chemical Dynamics

2. ScottS. K., Oscillations, waves and chaos in chemical kinetics. Oxford Chemistry Primers, Oxford University Press, Oxford, 18, 1994.

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