Affiliation:
1. Department of Chemistry, Mazandaran University, Babolsar, Iran
Abstract
A facile oxidative deprotection of trimethylsilyl and tetrahydropyranyl ethers in water using 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride as a new efficient reagent under neutral conditions is described. This methodology is ecofriendly and environmentally benign since it uses water as a solvent. In all reactions DABCO was regenerated, rechlorinated and reused several times.
Cited by
3 articles.
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1. Oxidation of alkyl benzenes to corresponding carbonyl compounds with 1,4-dichloro-1,4-diazoniabicyclo [2,2,2] octane bis-chloride in water;Journal of Chemical Research;2009-11
2. Chlorination of 3-substituted sydnones using 1,4-dichloro-1,4-diazoniabicyclo[2,2,2]octane bis-chloride;Journal of Chemical Research;2008-11
3. ChemInform Abstract: Oxidative Deprotection of Tetrahydropyranyl and Trimethylsilyl Ethers in Water Using 1,4-Dichloro-1,4-diazoniabicyclo[2,2,2]octane Bis-Chloride under Neutral Conditions.;ChemInform;2008-01-15