Epoxidation of electron-deficient α,β-unsaturated carbonyl compounds over Keggin heteropoly compounds with aqueous H2O2-Reference-Cited by-同舟云学术

Epoxidation of electron-deficient α,β-unsaturated carbonyl compounds over Keggin heteropoly compounds with aqueous H2O2

Published:2005-11 Issue:11 Volume:2005 Page:716-718
ISSN:1747-5198
Container-title:Journal of Chemical Research
language:en
Short-container-title:Journal of Chemical Research

Author:

Gao Qiang¹,Ding Yong²,Liu Haitao¹,Suo Jishuan¹³

Affiliation:

1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences, Lanzhou 730000, China

2. College of Chemistry and Chemical Engineering, Lan zhou University, Lanzhou 730000, China

3. Chengdu Organic Chemicals Co., Ltd., Chinese Academy of Sciences, Chengdu, 610041, China

Abstract

The epoxidation of a variety of electron-deficient α,β-unsaturated carbonyl compounds has been studied using a series of heteropoly compounds and aqueous hydrogen peroxide in acetonitrile. Among the heteropoly compounds investigated, (CTP)3VMo12O40 showed the highest catalytic performance for the epoxidation of these compounds.

Publisher

SAGE Publications

Subject

General Chemistry

Link

http://journals.sagepub.com/doi/pdf/10.3184/030823405774909289

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