Affiliation:
1. School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an, Jiangxi, 343009, P.R. China
Abstract
An unprecedented quaternary metal chalcogenide hg3Zn2S4I2 (1) has been obtained by solid-state reaction and structurally characterised by X-ray diffraction. Compound 1 crystallises in the space group C2221 of the orthorhombic system with four formula units in a cell: a = 12.571(4), b = 7.258(3), c = 10.742(4) Å, V = 980.1(6) Å3, Hg3I2S4Zn2, M r = 1114.55, D c = 7.553 g cm−3, T = 123.15 K, F(000) = 1880 and R1/ wR2 = 0.0636/0.1658 for 542 observed reflections ( I > 2σ( I)) and 572 unique reflections. Compound 1 is characterised by a novel 3-D framework motif.
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2 articles.
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